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111 T-Mobile? 6:16 PM × chapter six ONLINE HOMEWO… ? 106kj 5) 635 kJ Question 9

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Question

111 T-Mobile? 6:16 PM × chapter six ONLINE HOMEWO… ? 106kj 5) 635 kJ Question 9 -16 60.0 mL of 0.350 M H2SO4 solution is mixed with 60.0 mL of 0.700 M NaOH solution in a coffee cup calorimeter of negligible heat capacity. The initial temperature of the two solutions are both at 23.0 degrees C. What is the final temperature? (What is the temperature change?) assume solutions have same specific heat and density as water. (s water 4.184 J/goC; d H20 = 1.00g/mL) H2504 + 2NaOH-> Na2SO4 + 2H2O ? Hrxn = 114 kj/mol rxn (1) 18.9 degrees C 2) 27.8 degrees C 3) 22.5 degrees C 2 of 12 completed Save for Later Submit

Explanation / Answer

moles of H2SO4 = 60 x 0.350 / 1000 = 0.021

moles of NaOH = 60 x 0.700 / 1000 = 0.042 mol

delta Hrxn = - 114 kJ/mol

H2SO4   +   2 NaOH    ---------------> Na2SO4   +   2 H2O

   1                  2

0.021           0.042

Q = - n x deltaHrxn

    = - 0.021 x 114

Q = 2.394 kJ

Q = m Cp dT

2394 = 120 x 4.184 x (Tf - 23)

Tf = 27.8

final temperature Tf = 27.8 oC