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Suppose the volume of the syringe is 27 cc. You measure the pressure as 1.37 atm

ID: 1702352 • Letter: S

Question

Suppose the volume of the syringe is 27 cc. You measure the pressure as 1.37 atm, and the temperature as 23.6o C. Assume: the diameter of the plunger on the syringe is 2.99 cm.

a)Find
- n, the number of moles of gas in the syringe: moles
- N, the number of molecules of gas in the syringe: molecules
- Use the molear mass of air given to calculate the mass of air in the syringe: kg

b)Supose you push push down the syringe so the volume is now 22.8 cc, with the temperature remaining unchanged. Find:
- the new pressure inside the syringe. atm
- the force exerted by the gas on the syringe: N

Explanation / Answer

The volume of the syringe is V1 = 27 cc = 2.7*10^-5 m^3

The pressure P1 = 1.37 atm = 1.39*10^5 Pa

The temperature is T1 = 23.6 C = 296.6 K

a)

According to ideal gas equation

P1V1 = nRT1

n is number of moles of gas

R is universal gas constant = 8.31 J/molK

(1.39*10^5)(2.7*10^-5) = n(8.31)(296.6)

n = 0.0015 mol

The number of molecules is given by N = nNA

NA is the Avagadro number = 6.02*10^23

N = 9.03*10^20 molecules

The number of mole is given by

n = m/M

m is mass of the gas

M is molecular mass of the gas = 28.96*10^-3 kg/mol

The mass of the air in the syringe is m = 0.0015*28.96*10^-3 = 4.34*10^-5 kg

b)

The final volume V2 = 22.8 cc = 2.28*10^5 m^3

As the process is isothermal

P1V1 = P2V2

(1.37 atm)(27 cc) = P2(22.8 cc)

P2 = 1.62 atm

The force exerted in the piston will be

F = P2*A

F = 1.64*10^5 Pa * 7.02*10^-4 m^2    (A = d^2/4)

F = 115.13 N

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