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Suppose the volume of the syringe is 49.5 cc. You measure the pressure as 2.01 a

ID: 2019318 • Letter: S

Question

Suppose the volume of the syringe is 49.5 cc. You measure the pressure as 2.01 atm, and the temperature as 22o C. Assume: the diameter of the plunger on the syringe is 1.8 cm.

a)Find
- n, the number of moles of gas in the syringe:____ moles
- N, the number of molecules of gas in the syringe:_____ molecules
- Use the molear mass of air given to calculate the mass of air in the syringe:____ kg

b)Supose you push push down the syringe so the volume is now 42.7 cc, with the temperature remaining unchanged. Find:
- the new pressure inside the syringe._____ atm
- the force exerted by the gas on the syringe:_______ N

Explanation / Answer

The volume of the syringe is V1 = 49.5 cc = 49.5*10^-5 m^3

The pressure P1 = 2.01 atm = 2.01*10^5 Pa

The temperature is T1 = 22 C = 295 K

a)

According to ideal gas equation

P1V1 = nRT1

n is number of moles of gas

R is universal gas constant = 8.31 J/molK

(2.01*10^5)(49.5*10^-5) = n(8.31)(295)

n = 0.040 mol

The number of molecules is given by N = nNA

NA is the Avagadro number = 6.02*10^23

N = 240.8*10^20 molecules

The number of mole is given by

n = m/M

m is mass of the gas

M is molecular mass of the gas = 28.96*10^-3 kg/mol

The mass of the air in the syringe is m = 0.0015*28.96*10^-3 = 1.15*10^-3 kg

b)

The final volume V2 = 42.7 cc = 42.7*10^-5 m^3

As the process is isothermal

P1V1 = P2V2

(2.01 atm)(49.5 cc) = P2(42.7 cc)

P2 = 2.33 atm

The force exerted in the piston will be

F = P2*A

F = 2.33*10^5 Pa * 10.1*10^-4 m^2    (A = d^2/4)

F = 235.3 N

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