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(1a) An aqueous solution is made by dissolving 26.7 grams of sodium bromide in 4

ID: 487197 • Letter: #

Question

(1a) An aqueous solution is made by dissolving 26.7 grams of sodium bromide in 427 grams of water.

The molality of sodium bromide in the solution is= m.

(b)In the laboratory you are asked to make a 0.704 m manganese(II) iodide solution using 475 grams of water.

How many grams of manganese(II) iodide should you add? =
grams.

(c)In the laboratory you are asked to make a 0.150 m manganese(II) nitrate solution using 13.9 grams of manganese(II) nitrate.

How much water should you add? =
grams

(2a) An aqueous solution is 16.0% by mass potassium bromide, KBr, and has a density of 1.12 g/mL.

The molality of potassium bromide in the solution is= m.

(b) An aqueous solution of iron(II) sulfate has a concentration of 0.221 molal.

The percent by mass of iron(II) sulfate in the solution is = %.

(c) An aqueous solution is 13.0% by mass potassium bromide, KBr, and has a density of 1.10 g/mL.

The molality of potassium bromide in the solution is = m

Explanation / Answer

1)

a)

Molar mass of NaBr,

MM = 1*MM(Na) + 1*MM(Br)

= 1*22.99 + 1*79.9

= 102.89 g/mol

mass(NaBr)= 26.7 g

use:

number of mol of NaBr,

n = mass of NaBr/molar mass of NaBr

=(26.7 g)/(1.029*10^2 g/mol)

= 0.2595 mol

m(solvent)= 427 g

= 0.427 kg

use:

Molality,

m = number of mol / mass of solvent in Kg

=(0.2595 mol)/(0.427 Kg)

= 0.6077 molal

Answer: 0.608 molal

b)

m(solvent)= 475 g

= 0.475 kg

use:

number of mol,

n = Molality * mass of solvent in Kg

= (0.704 mol/Kg)*(0.475 Kg)

= 0.3344 mol

Molar mass of MnI2,

MM = 1*MM(Mn) + 2*MM(I)

= 1*54.94 + 2*126.9

= 308.74 g/mol

use:

mass of MnI2,

m = number of mol * molar mass

= 0.3344 mol * 3.087*10^2 g/mol

= 1.032*10^2 g

Answer: 103 g

c)

Molar mass of Mn(NO3)2,

MM = 1*MM(Mn) + 2*MM(N) + 6*MM(O)

= 1*54.94 + 2*14.01 + 6*16.0

= 178.96 g/mol

mass(Mn(NO3)2)= 13.9 g

use:

number of mol of Mn(NO3)2,

n = mass of Mn(NO3)2/molar mass of Mn(NO3)2

=(13.9 g)/(1.79*10^2 g/mol)

= 7.767*10^-2 mol

use:

Molality,

m = number of mol / mass of solvent in Kg

0.150 = (7.767*10^-2 mol) / mass of solvent in Kg

mass of solvent = 0.5178 Kg

mass of solvent = 517.8 g

Answer: 518 g

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