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The reaction of 0.194 g of Zn with HCl_(aq) gave 80.3 mL (at 23.4 degree C) of h

ID: 515841 • Letter: T

Question

The reaction of 0.194 g of Zn with HCl_(aq) gave 80.3 mL (at 23.4 degree C) of hydrogen gas collected over water in a gas tube. The water was 18.5 mm higher in the gas tube than it was in the beaker (step C). The barometer reading is 698. mm Hg. Following the steps on pages 1 to 3, complete this table of data. A. Mass of Zn B. Volume of H_2 Gas Generated C. Height of water Column inside tube (mm H_2 O) D. Temperature of H_2 Gas E. Vapor Pressure of Water F. Atmospheric Pressure (mm Hg) G. Adjustment for water in tube: "C." times 1 mm Hg/13.5 mm H_2 O H. Total Pressure inside gas tube (mm Hg) (F-G) I. Pressure of hydrogen inside gas tub (mm Hg) (H - E) J. Pressure of hydrogen in atm K. Moles of Hydrogen from PV = nRT L. Balanced Chemical Equation M. Calculated Molar Mass of Zinc

Explanation / Answer

A. Mass of Zn:                                                                                                                                65.37 g/mol

B. Volume of H2 gas generated                                                                                                            80.3 ml

C. Height of water column inside tube                                                                                                18.5 mm

D. Temerature of H2 gas                                                                                                                       23.4 oC

                                                                                                                                      273.15+23.4= 296.55 K

E. Vapor pressure of water                                                                                                                716.5 mm?

F. Atmospheric pressure (mm Hg)                                                                                                         690 mm

G. Adjustment for water in tube 'C' 18.5 mm x 1mm/ 13.5 mm H2O                                                  1.39 mm?

H. Total pressure inside gas tube  690 mm + 1.39 mm                                                                   691.39 mm?

I. Pressure of hydrogen inside gas tube

J. Pressure of hydrogen in atm

K. Moles of hydrogen from PV =nRT

  Or it should be equal to no. of moles of Zinc used in the reaction according to balanced equation = 0.00296 mol  

L. Balanced chemical equation:

             Zn (s) + 2 HCl (aq) ------------------------> H2 (g) + ZnCl2 (aq)

M. Calculated molar mass of Zinc                                   0.194 g / 65.37 g = 0.00296 moles or 2.96 mmoles

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