a-donor, or a-donor/t-acceptor) by circling the appropriate abbreviation in the
ID: 520610 • Letter: A
Question
a-donor, or a-donor/t-acceptor) by circling the appropriate abbreviation in the rightmost column lable Table 1. Molar Absorbance Absorptivity.e- concentration "C" A" at (L moli cm 1). (mol/L) Ama (nm) A" (cm 1) Ligand Donor Type Complex Color ad/Ta 193 [Co (NH) ad/nd ad ad/ita .323- ad/nd ad Cad 2395 ad/td od ad/ita [Co (ox)3] d/md ad ad/ [Co(H2O)6]3 ad/md od ad/Tan Co(acac)s 10 [Ni(en) ad/Td ad ad/ita [Ni(H20)6] ad ad/ita (Ni(DMSO) ad/td ad ad/ita ad ad/ Ta ad/Td ad ad/ita Cr(acac)3 using values above for each complex, put the ligands in order of increasing ligand field, thereby experimentally determining the the spectrochemical series. You will have to intersperse ligands from separate metal series to develop an overall spectrochemicalExplanation / Answer
After interspersing ligands from different metals and making a separate spectrochemical series, we get:
(CO3)2- < ox < DMSO < acac < H2O < gly < NH3 < Im < en < bpy < NO2- < CN-
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