To identify the oxidation numbers of hydrogen and oxygen in compounds. Hydrogen
ID: 522359 • Letter: T
Question
To identify the oxidation numbers of hydrogen and oxygen in compounds.
Hydrogen has three possible oxidation numbers:
1 when bonded to a metal,
0 when in elemental form, H2, and
+1 when bonded to a nonmetal.
Oxygen has several possible oxidation numbers:
2 when bonded to a nonmetal (other than fluorine) or as the oxide ion, O2,
1 as the peroxide ion, O22,
1/2 as the superoxide ion, O2, and
0 when in elemental form, O2 or O3.
Disproportionation is a type of redox reaction in which the same element is both oxidized and reduced. For example, H2 can undergo disproportionation because some of the H atoms can be reduced from 0 to 1 and some can be oxidized from 0 to +1. However, hydrogen in the +1 state cannot undergo disproportionation because it can only be reduced, not oxidized. Similarly, hydrogen in the 1 state can only be oxidized, not reduced.
1. Classify each of the following binary compounds by the oxidation number of oxygen.
Drag each item to the appropriate bin.
-2
-1
-1/2
0
2. Which of the following forms of oxygen can undergo disproportionation?
Check all that apply.
oxide ion peroxide ion superoxide ion CaOExplanation / Answer
(1)
CaO
O.S = -2, Oxide
KO2
O.S = -1/2, superoxide
O2
O.S = 0, element
CO2
O.S = -2, oxide
K2O
O.S = -2 , oxide
CaO2
O.S = -1, peroxide
K2O2
O.S = -1, Peroxide
O3
O.S = 0, element
(2)
Peroxide can undergo dispropotionation reaction. Here O- can be oxidised to zero and can be reduced to -2.
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