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and after a series of dilutions the Experiment 39 Prelaboratory Date Lab Sec. 1.

ID: 592356 • Letter: A

Question

and after a series of dilutions the Experiment 39 Prelaboratory Date Lab Sec. 1. Identify the reagent (and its concentration) that is unedo untm the pera Desk No. a. Ni m the presence of each of the fohowing 2. Confirmatory tests for each of the following ions: the various ions conpoundion and the coloe fon are often colorful. Identify the confirmatory Confirmatory Compou nd/lon Color Fe'+ Rosr k Al+ 3. Identify the reagent that separates a. Fe from Zn2". Explain the chemistry of the separation. b. Fe from Ni+. Explain the chemistry of the separation. c. Al+ from Zn2. Explain the chemistry of the separation.

Explanation / Answer

Q1

reagent which will identify the ions:

a)

Ni2+ will form a red-colored preicpitate when we add dimethylglyoxime , DMG

note that this mus be in basic solution

Ni+2 + 2 HDMG --> Ni(DMG)2 + 2 HNO3

b)

Fe+3 will form a complex of red-brown color, Fe(SCN)+2

then, add

Fe+3 + NaSCN(aq) = Fe(SCN)+2(aq)(red) + Na+

c)

Zn2+ ion precipitate with S2- ions therefore

Zn2+(aq) + S-2(aq) = ZnS(s)