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Based on the values for the Van Der Waals equation, determine an approximate mol

ID: 623130 • Letter: B

Question

Based on the values for the Van Der Waals equation, determine an approximate molecular volume for CCl4. Rationalize these values based on reasonable bond lengths and other parameters. The Lennard-Jones potential energy function is often used to model interactions between molecules. One form is: V(r)=4Epsilon[(sigma/R)^12 - (sigma/R)^6] For Cl, Epsilon=357/k and sigma=4.115 Angstrom For H, Epsilon=33.3/k and sigma=2.968 Angstrom Plot and overlay these functions. Comment on Van der Waals a and b values from a stat table, and the information in these plots

Explanation / Answer

2. Relevant equations V(r) = 4e [{s/R}^12 - {s/R}^6] For Cl, e = 357/k, s = 4.115 Angstrom For H, e = 33.3/k, s = 2.968 Angstrom

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