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QuestionDetails: Determine the pH of each of the following solutions A) 0.095 M

ID: 684488 • Letter: Q

Question

QuestionDetails: Determine the pH of each of the following solutions A) 0.095 M hypochlorous acid   Ka= 3.0 x 10-8 B) 0.0085 Mphenol          Ka = 1.3 x 10-10 C) 0.095 M hydroxylamine   Ka= 1.1 x 10-8 QuestionDetails: Determine the pH of each of the following solutions A) 0.095 M hypochlorous acid   Ka= 3.0 x 10-8 B) 0.0085 Mphenol          Ka = 1.3 x 10-10 C) 0.095 M hydroxylamine   Ka= 1.1 x 10-8 QuestionDetails: Determine the pH of each of the following solutions A) 0.095 M hypochlorous acid   Ka= 3.0 x 10-8 B) 0.0085 Mphenol          Ka = 1.3 x 10-10 C) 0.095 M hydroxylamine   Ka= 1.1 x 10-8

Explanation / Answer

           A)                 HOCl H+   + Cl-              I(M)     0.095M      0         0              C(M)       -x          x          x              E(M)     0.095-x      x        x                        Ka = [H+] [Cl-] / [HOCl]                        3.0 x 10-8 = x2 / 0.095-x               bysolving x   = [H+] =   5.33 x 10-5 M                   pH = -log [H+] =  4.273.      B)              PhOH    H+  + PhO-                             I(M)     0.0085M      0         0              C(M)         -x          x          x              E(M)    0.0085-x      x         x                        Ka = [H+] [PhO-] / [PhOH]                         1.3x 10-10 = x2 / 0.0085-x               bysolving x   = [H+] =   1.051 x 10-6 M                   pH = -log [H+] =  5.978.        c)             NH2OH NH2+ +OH-                   I(M)     0.095M      0         0               C(M)       -x          x          x              E(M)    0.095-x      x         x                       Kb = x2 / 0.095-x                         1.1x 10-8 = x2 / 0.095-x               bysolving x   = [OH-] =  3.23 x 10-5 M                   pOH = -log [H+] =  4.490                pH = 14 - 4.490 = 9.509               C(M)       -x          x          x              E(M)    0.095-x      x         x                       Kb = x2 / 0.095-x                         1.1x 10-8 = x2 / 0.095-x               bysolving x   = [OH-] =  3.23 x 10-5 M                   pOH = -log [H+] =  4.490                pH = 14 - 4.490 = 9.509               C(M)       -x          x          x              E(M)    0.095-x      x         x                       Kb = x2 / 0.095-x                         1.1x 10-8 = x2 / 0.095-x               bysolving x   = [OH-] =  3.23 x 10-5 M                   pOH = -log [H+] =  4.490                pH = 14 - 4.490 = 9.509
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