18 Chemistry 103 Finals NAME DATE SHOW SET UP AND SOLUTION 1. Determine the mole
ID: 699073 • Letter: 1
Question
18 Chemistry 103 Finals NAME DATE SHOW SET UP AND SOLUTION 1. Determine the molecular formula of a compound that contains 66 e% c. 11 and has a molecular weight of 72 2. A compound contains only carbon, hydrogen, and nitrogen. After combustion of a 0 500 ssmple, the mass of the first trap (collecting H/0) Increases by 0.698 g and the mass of the ond trap (collecting COl Increases by 0 977 E: What is the emplrical formuia of this compourd? ANS 3. What is the molecular formula of a substance that contains only 0.801 g of carbon and 0.10 of hydrogen and has a molecular weight of 54? 4. Given the following equation, calculate the mass of O: needed to react completelyyw NO. 2NO + O2 2NO2Explanation / Answer
1) we have given molecular weight of unkonown compound is 72
there are percentage given so,
Amount of C : Amount of H : Amount of O = 66.6 : 11.2 : 22.2
Atoms of C : Atoms of H : Atoms of O
atoms of C = 66.6/12 = 5.55
atoms of H = 11.2/1.008 = 11.11
atoms of O = 22.2/16 = 1.3875
now we convert in simple ration = 4 : 8 : 1
molecular formula will be = C4H8O
2) write the chemical equation
CxHyNz + O2 --> CO2 + H2O + NH3
With x , y and z is unknown
C = 12 g/mol
O2 = 32 g/mol
H = 1 g/mol
N = 14 g/mol
CO2 = 44 g/mol
H2O = 18 g/mol
NH3 = 17 g/mol
44 g CO2 is produced from 12 g C
0.977 g CO2 is produced from = (12)(0.977) / 44 = 0.266 g C present in 0.5 g compound.
18 g H2O is produced from 2 g H
0.698 g H2O is produced from = (2)(0.698) / 18 = 0.0775 g H present in 0.5 g compound.
now remainig will be N = 0.5 - (0.266 +0.0775) = 0.1564 g
no. of moles of C = (0.266 g / 12 g/mol ) = 0.02216
no. of moles of H = (0.0775 g / 1.0 g/mol ) = 0.0775
no. of moles of N = (0.1564 g / 14 g/mol) = 0.01117
ratio of C : H : N = 2 : 7 : 1
molecular formula will be = C2H7N
x = 2 , y = 7 and z = 1
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