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virgina Community Col x®GChegg Study I Guided Sc x eAssignment/takeCovalentActiv

ID: 704111 • Letter: V

Question

virgina Community Col x®GChegg Study I Guided Sc x eAssignment/takeCovalentActivity.do?locators assignment-take&itakeAssignmentSessionLocator; assignment-take In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35 °C, primary, secon tertiary C-H bonds react at relative rates of 1:3.9: 5.2 respectively These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if A is for twice as fast as B, the A:B product ratio will be 2 Consider chlorination of the alkane below at 35°C 1. Specify the most reactive C-H bond), a Two non-equivalent C-H b bonds of comparable reactivity should be separated by commas,ie. a,c 2 Specify the site of chlorination in the major monochloro substitution product, a-c. Two products that form in comparable quantities should be separated by commas, i.e. ac Submil Answer Retry Entire Group 8 more group attempts remaining Nen

Explanation / Answer

1. 1. B, since it has secondary C-H hydrogen and more stable by hyper conjugation than C.

2. Site B forms major monochlorinated compound

2. 1. C, since it has more reactive C-H bond

2. Site C forms more amount of monochlorinated product

3. A. 4

B.2