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An irreversihle reaction (2A - B) is performerd in an isothermal, variahle volum

ID: 717937 • Letter: A

Question

An irreversihle reaction (2A - B) is performerd in an isothermal, variahle volume continuous- stirred tank reactor (CSTR). A feed stream containing pure reactant A enters the CSTR at a volumetric flow rate o and molar concentration CAD. The product stream leaves the reactor at a volumetric flow rate q with reactant and product concentrations of CA and C3. The reaction rate of A per unit volume is r- kCA5. Assume the feed and product streams have the same densities (a) Derive a dynamic model for the CSTR. (b) Perform a degrees of freedom analysis (c) Identify the model constants, input variables and output variables (d) Ifqo and CAo are disturhances, propose a control strategy for the CSTR, and clearly identify the controlled and manipulated variables. Draw a schematic P&ID diagram (not a block diagram) of the control system. Clcarly labcl and usc appropriate symbols for all of the omponents of the control system. 1o. hCA q. CA, CB

Explanation / Answer

Inlet volumetric flow rate = qo

Initial molar concentration = CAo

Outlet volumetric flow rate = q

Reactant molar concentration = CA

Product molar concentration = CB

rate per unit volume: r = k CA0.5, tank volume = V,

density of feed and product streams are same = D

a) Derive a dynamic model for the CSTR

Total Mass Balance:

Rate of accumulation of mass in tank = rate of mass in - rate of mass out

d(DV)/dt = D*qo - D*q. {D = density is constant}

dV/dt = qo - q —————————(1) Component Balance:

Component Balance for A:

IN - OUT - Generation = Accumulation

qoCAO - qCA - rV = d/dt(CAV)

qoCAO - qCA - rV = CA*d(V)/dt + V*d(CA)/dt

put dV/dt from equateon (1):

qoCAO - qCA - rV = CA(qo - q) + V*dCA/dt

V*dCA/dt = qoCAO - qCA - rV - CA*qo + CA*q

dCA/dt = (qoCAO - kCA0.5 - CA*qo)/V ——————{ r = rate/Volume)

Component Balance for B:

IN - OUT - Generation = Accumulation

0 - qCB + r.V = d/dt(CBV)

dCB/dt = (kCA0.5 - qCB)/V ——————{ r = rate/Volume)

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