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13. The following cobalt complexes absorb at 700, 600, 500, 475, 310. Given the

ID: 799220 • Letter: 1

Question

13. The following cobalt complexes absorb at 700, 600, 500, 475, 310. Given the following spectrochemical series: F<H2O<NH3<CN, which lists the complexes in the correct order from highest wavelength to lowest?

[Co(CN)6]3-, [Co(NH3)]3+, [Co(NH3)5H2O]3+, [Co(H2O)6]3+, CoF63-

[Co(CN)6]3-, [Co(NH3)]3+, [Co(H2O)6]3+, [Co(NH3)5H2O]3+, CoF63-

[Co(NH3)]3+, [Co(H2O)6]3+, [Co(NH3)5H2O]3+, CoF63-, Co(CN)6]3-

CoF63- [Co(NH3)5H2O]3+, [Co(H2O)6]3+, [Co(NH3)]3+, [Co(CN)6]3-

CoF63-, [Co(H2O)6]3+, [Co(NH3)5H2O]3+, [Co(NH3)]3+, [Co(CN)6]3-

CoF63-, [Co(NH3)5H2O]3+, [Co(NH3)]3+, [Co(H2O)6]3+, [Co(CN)6]3-

Please show all work, thank you

Explanation / Answer

CoF63-, [Co(H2O)6]3+, [Co(NH3)5H2O]3+, [Co(NH3)]3+, [Co(CN)6]3-

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