Give a formula for each of the following coordination compounds or complexes, an
ID: 864608 • Letter: G
Question
Give a formula for each of the following coordination compounds or complexes, and give the number of d electrons on the transition metal:
a. Bis(bipyridyl)(1,10-phenanthroline)ruthenium (2+) chloride (use abbreviations forligands in formula)
b. Tetraamminehydroxoiodocobalt (II)
c. Pentaamminechlororuthenium (2+) tetrafluoroborate (tetrafluoroborate is a complex ion with a -1 charge)
d. Tetraamminediaquaruthenium (II)
e.cis-diamminedichloroplatinum (II) (the chemotherapy agent "cisplatin.")
f. Dichlorobis(triphenylphosphane)rhodium (II)
g. Dinitritotetrakis(4-methylpyridine)nickel (II)
Explanation / Answer
a) [Ru(bipy)2(phen)]Cl2. Number of d electrons of Ru2+ are 3d10 and 4d4
b) [Co(NH3)4(OH)(I)] Number of d electrons of Co2+ are 7
c) [Ru(NH3)5Cl]BF4 Number of d electrons of Ru2+ are 3d10 and 4d4
d) [Ru(NH3)4(H2O)2]2+ Number of d electrons of Ru2+ are 3d10 and 4d4
e) cis-[Pt(NH3)2Cl2] Number of d electrons of Pt2+ are 5d8
f) [Rh((C6H5)3P)2Cl2] Number of d electrons of RH2+ are 4d7
g) [Ni(NO)2(MePy)4] Number of d electrons of Ni2+ are 3d8
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