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1)To prevent the presence of air, noble gases are placed over highly reactive ch

ID: 895184 • Letter: 1

Question

1)To prevent the presence of air, noble gases are placed over highly reactive chemicals to act as inert "blanketing" gases. A chemical engineer places a mixture of noble gases consisting of 4.66 g of He, 15.8 g of Ne, and 36.6 g of Kr in a piston-cylinder assembly at STP. Calculate the partial pressure of each gas.
PHe =     atm
PNe =   atm
PKr =    atm

2) When 36.6 L ammonia and 38.5 L oxygen gas at STP burn, nitrogen monoxide and water are produced. After the products return to STP, how many grams of nitrogen monoxide are present?
- g

Explanation / Answer

2. 4 NH3 + 5 O2 ---> 4 NO + 6 H2O

Since 1 mole of any gas at STP is 22.4 liters, you can calculate moles of NH3 as:

36.6L/22.4l/mole = 1.63mole

Because the volume of O2 is specified (not excess), we need to see which reagent is the limiting reagent:

Moles of O2 are:

38.5LO2/22.4 liters/mole = 1.71 moles O2

Because we need 5 O2's for each 4 NH3, to react all the NH3 we would need:

1.63 mol NH3 x (5moles O2/4moles NH3) = 2.03 moles O2

We only have 1.71 moles O2, so not all the NH3 will react; we will only produce;

1.71 x (4 mole NO/5moleO2) = 1.36 moles of NO

Now multiply moles by molecular weight of NO to get grams:

1.36 moles NO x (16.0 + 14.01) = 40.8 g NO