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I conduted the following experiment. How do you determine the concentration of v

ID: 916859 • Letter: I

Question

I conduted the following experiment. How do you determine the concentration of vinegar?

Data Table 1. NaOH Titration Volume.

Initial NaOH Volume (mL)

Final NaOH Volume (mL)

Total volume of NaOH used (mL)

Trial 1

9

4

5

Trial 2

5.2

1.2

4.2

Trial 3

6.4

1

5.4

Average Volume of NaOH Used (mL) : 4.867 mL

Data Table 2. Concentration of CH3COOH in Vinegar.

Average volume of NaOH used (mL)

Concentration CH3COOH in vinegar (mol/L)

% CH3COOH in vinegar  

4.867

Show your calculations here:

Questions

The manufacturer of the vinegar used in the experiment stated that the vinegar contained 5.0% acetic acid. What is the percent error between your result and the manufacturer’s statement?

Initial NaOH Volume (mL)

Final NaOH Volume (mL)

Total volume of NaOH used (mL)

Trial 1

9

4

5

Trial 2

5.2

1.2

4.2

Trial 3

6.4

1

5.4

Average Volume of NaOH Used (mL) : 4.867 mL

Explanation / Answer

Given

Average volume of NaOH = 4.867 mL

[NaOH]= 0.5 M

Volume of acetic acid = 5.0 mL

Lets write reaction between NaOH and CH3COOH

CH3COOH + NaOH -- > CH3COONa + H2O

Mol ratio is 1:1

So we can simply use M1V1 = M2V2

Let M1= Molarity of acid

V1=volume of acid

M2 = molarity of base

V1 = volume of base

M1 = M2V2/V1

= 0.5 M x 4.867 mL / 5.0 mL

= 0.487 M

[CH3COOH]= 0.487 M

Percent error=[ (Accepted value – experimental value )/ accepted value ] x 100

Here lets find Molarity of 5 % acetic acid

Lets assume volume of solution = 1000 mL = 1.000 L

Percent of acetic acid is 5 so we can find mass of it

Mass of acetic acid in 1000 mL

= 1000 mL x 5 g / 100 mL

= 50 g

Moles of acetic acid = 50.0 g / molar mass of acetic acid

= 5.0 g x 1 mol / 60.05 g

=0.832 mol

Molarity =0.832 mol / 1 L = 0.832 M

Percent error = ( 0.832 M – 0.487 M ) / 0.832 M ] x 100

= 41.5 %

Percent error = 41.5 %   

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