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Suppose a dimer, A2, reacts by first dissociating into its monomers and is trans

ID: 927761 • Letter: S

Question

Suppose a dimer, A2, reacts by first dissociating into its monomers and is transformed into B by the following mechanism. Assume a steady state approximation for A and derive a rate expression for the appearance of B. Integrate this expression to obtain the integrated rate law for the appearance of Assume a pre-equilibrium approximation and derive the rate expression for the appearance of B in terms of A2. Integrate this expression to obtain the integrated rate law for the appearance of B, which differs in the expression for k from the integrated expression for part (a).

Explanation / Answer

Suppose a dimer, A2, reacts by first dissociating into its monomers and is trans

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