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1. Lead crystallizes in a face-centered cubic unit cell with an edge length of 4

ID: 937741 • Letter: 1

Question

1. Lead crystallizes in a face-centered cubic unit cell with an edge length of 495 pm. What is the radius of a lead atom in picometers? What is the density of lead in g/cm3?

2. Aluminum has a density of 2.699 g/cm3 and crystallizes with a face-centered cubic unit cell. What is the edge length of a unit cell in picometers?

3.Tungsten crystallizes in a body-centered cubic unit cell with an edge length of 317 pm. What is the length in picometers of a unit-cell diagonal that passes through the center atom?

Explanation / Answer

1.

edgelength = a = 495 pm =

volume of the unit cell = a^3 = (495*10^(-10))^3 = 1.213*10^(-22) cm

Density = ZM/a^3 Na

        = 4*207.2 /(1.213*10^(-22)*6.023*10^23)

      = 11.34 g/cc

2. 2.699 = 4*27/(a^3*6.023*10^23)

a = edge length = 4.05*10^-8 cm


3. a = 317 pm

diagonal length = sqrt 3a

   = (sqrt3)*317
  
= 549.06 pm