What is the vapor pressure of an aqueous ethylene glycol (C_2H_6O_2) solution th
ID: 939531 • Letter: W
Question
What is the vapor pressure of an aqueous ethylene glycol (C_2H_6O_2) solution that is 14.8% C_2H_6O_2 by mass? The vapor pressure of pure water at 25 degreeeC is 23.8 torr. a) 3.52 torr b) 22.7 torr c) 1.14 torr d) 20.3 torr 8. A solution contains a mixture of two volatile substances A and B. The mole fraction of substance A is 0.35. At 32 degreeC the vapor pressure of pure A is 87 mmHg and the vapor pressure of pure B is 122 mmHg. What is the total vapor pressure of the solution at this temperature? a) 110 mmHg b) 209 mmHg c) 99.3 mmHg d) 73.2 mmHgExplanation / Answer
answer : option B) 22.7 torr
glycol mass = 14.8 g
glycol moles = 14.8 / 62 = 0.239 = n1
water moles = 85.2 / = 4.73 = n2
mole fraction of glycol = n1 / n1 + n2 = 0.239 / 0.239 + 4.73 = 0.048
Po - PS / Po = mole fraction
23.8 - Ps / 23.8 = 0.048
Ps = 22.7 torr
8) answer : option A ) 110 mmHg
Psoltion = PAXA + PBXB
= 87 x 0.35 + 122 x 0.65
= 110 mmHg
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