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What is the final concentration of D at equilibrium if the initial concentration

ID: 951565 • Letter: W

Question

What is the final concentration of D at equilibrium if the initial concentrations are [A] = 1.00 M and [B] = 2.00 M ?The reversible chemical reaction

A+BC+D

has the following equilibrium constant:

Kc=[C][D][A][B]=5.3

Gaseous hydrogen iodide is placed in a closed container at 425C, where it partially decomposes to hydrogen and iodine:

2HI(g)H2(g)+I2(g)

At equilibrium it is found that [HI]= 3.55×103M, [H2]= 4.82×104M , and [I2]= 4.82×104M.

What is the value of Kc at this temperature?

b

The reversible chemical reaction

A+BC+D

has the following equilibrium constant:

Kc=[C][D][A][B]=5.3

a

Initially, only A and B are present, each at 2.00 M. What is the final concentration of A once equilibrium is reached?

b

What is the final concentration of D at equilibrium if the initial concentrations are [A] = 1.00 M and [B] = 2.00 M ?

Explanation / Answer

                A + B   C   +   D

initially     1       2         0         0

at equi (1 - X) (2 - X) X        X

Kc=[C] [D] / [A] [B] = 5.3 = (x) *(x) / ((1-x)*(2-x))

x = 0.8726 = [D]

                 2 HI (g)         H2 (g)   +      I2 (g)

at equi   3.55×103        4.82×104      4.82×104

Kc = [HI]^2 / [H2] [I2]

Kc = (3.55 * 10^-3)^2 / (4.82*10^-4)^2

Kc = 54.2453

   A + B   C   +   D

initially     2       2         0         0

at equi (2- X) (2 - X) X        X

Kc=[C] [D] / [A] [B] = 5.3 = (x) *(x) / ((2-x)*(2-x))

x = 1.3943 = [D]

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