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What is the theoretical yield for Co II (salen)? H 2 (salen) + [Co II (OAc) 2 ]

ID: 988634 • Letter: W

Question

What is the theoretical yield for CoII(salen)? H2(salen) + [CoII(OAc)2] * 4H2O ------> CoII(salen) * 2H2O

Experiment Guide:

Synthesis of CoII(salen) complex • In a 250 mL Erlenmeyer flask, stir 10 mmol H2salen (2.68 g) in 40 mL of ethanol under reflux (boiling). • Add 10 mmol cobalt(II) acetate tetrahydrate [CoII(OAc)2•4H2O, 2.49 g] slowly. • After stirring for 30 min, let the solution cool to near room temperature. Pay attention to the color change during this step. • Recover the solid product by suction filtration through filter paper in a Büchner funnel on a filter flask. Rinse with diethyl ether. • Determine the yield of the dry solid

Explanation / Answer

10 mmol H2salen (2.68 g) and 10 mmol cobalt(II) acetate tetrahydrate will give 10 mmol of CoII(salen) * 2H2O

Molecular formula of CoII(salen) = C16H18CoN2O4

Molar mass of C16H18CoN2O4 is 361.2583 g/mol
weight of 10 mmol of CoII(salen) = 10 x 361.2583 = 3.612583 gm

theoretical yield for CoII(salen) is = 3.612583 gm

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