By mass spectral analysis, a sample of strontium is known to contain 2.64times10
ID: 992946 • Letter: B
Question
By mass spectral analysis, a sample of strontium is known to contain 2.64times10^10 atoms of Sr-90 as the only radioactive element. The absolute disintegration rate of this sample is measured as 1238 disintegrations per minute. Calculate the half-life (in years) of Sr-90. How long will it take (in years) for the disintegration rate of this sample to drop to 829 disintegrations per minute? In a living organism, the decay of C-14 produces 15.3 disintegrations per minute per gram of carbon. The half-life of C-14 is 5730 years. A bone sample with 2.5 g of carbon has 19.8 disintegrations per minute. How old is the bone sample in years? When^239Pu is used in a nuclear reactor, one of the fission events that occurs is The atomic mass of each atom is given below its symbol in the equation. Find the energy released (in kJ) when 4.50 g of plutonium undergoes this particular fission. (1) Calculate the change in mass, expressed in atomic mass units, that accompanies this fission event. (2) Convert the mass loss to joules per fission. (3) Find the energy released per mole of plutonium... One of the fission products that causes major concern is Sr-90, since it is incorporated into milk and other high-calcium foods. Sr-90 undergoes beta decay with a half-life of 28.1 years. What percentage of the Sr-90 that was formed in the detonation of the first fission bombs in August 1945 is still present in the environment in August 2027?Explanation / Answer
29)
A = k x N
A = activity
k = decay constant
N = number of atoms
so
1238 = k x 2.64 x 10^10
k = 4.69 x 10-8
now
half life = ln2 / k
half life = ln2 / 4.69 x 10-8
half life = 1.478 x 10^7 min
1 yr = 525600 min
so
half life = 1.478 x 10^7 / 525600
half life = 28.12 years
30)
now
ln (A/Ao) = -k x t
so
ln ( 829 / 1238) = - 4.69 x 10-8 x t
t = 8.55 x 10^6 min
t = 8.55 x 10^6 / 525600
t = 16.27
so
it takes 16.27 years
31)
we know that
decay constant (k) = ln2 / half life
k = ln2 / 5730
k = 1.21 x 10-4
now
A = disintegrations per minute per gram = 19.8 / 2.5 = 7.92
now
ln (A/Ao) = -kt
ln ( 7.92 / 15.3) = - 1.21 x 10-4 x t
t = 5443.266
so
bone sample is 5443.266 years old
35)
mass defect (dm) = mass of reactants - mass of products
mass defect = ( 1.008665u + 239.052u) - ( 95.916u + 139.917u + 4 x1.008665u)
dm = 0.193005u
now
dE = dm x 931.5 MeV
dE = 0.193005 x 931.5
dE = 179.784 MeV
now
1 MeV = 1.6 x 10-13 J
so
dE = 179.784 x 1.6 x 10-13 J
dE = 2.876 x 10-11 J
dE = 2.876 x 10-14 kJ
this is for one atom of plutonium
now
number of atoms fo Plutonium = mass x 6.023 x 10^23 / atomic mass
number of atoms of plutonium = 1.1338 x 10^22
now
total energy released = 1.1338 x 10^22 x 2.876 x 10-14
total energy released = 3.26 x 10^8 kJ
so
3.26 x 10^8 kJ of energy is released
36)
decay constant (k) = ln2 / half life
decay constant (k) = ln2 / 28.1 = 0.024667
now
ln ( N/No) = -kt
ln (N/No) = - 0.024667 x 82
N/No = 0.1323
(N/No) x 100 = 0.1323 x 100
(N/No) x 100 = 13.23
so
13.23% still remains
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