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5/10/2016 11:55 PM A 107/15 5/5/2016 01:08 PM re Print calculator Periodic Table

ID: 996495 • Letter: 5

Question

5/10/2016 11:55 PM A 107/15 5/5/2016 01:08 PM re Print calculator Periodic Table Gradebook Question 4 of 9 pling learning Map deb A cell composed of a platinum indicator electrode and a silver-silver chloride reference electrode in a solution containing both Fe and Fes has a cell potential of 0.741 v. lf the silver-silver chloride electrode is replaced with a saturated what is the new cell potential? Number o Previous Give up & View solution check Answer Next Exit Resor Gra up on You you O eTex O Help owee O Techn

Explanation / Answer

The potential of a silver:silver chloride reference electrode with respect to the standard hydrogen electrode depends on the electrolyte composition.

Lets consider, Ag/AgCl/Sat. KCl+0.197

E = E+(cathode) - E-(anode)

0.741 = E+(cathode) - 0.197
E+(cathode) = 0.938 V

when switch with calomel, Saturated calomel electrode (SCE) (E=+0.241 V saturated)

E = 0.938 - 0.241= 0.697V

given that E = 0.741 V
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