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A student is given unknowns to identify. Options: HCl NaOH NH4OH BaCl2 K2CrO4 Ag

ID: 1002833 • Letter: A

Question

A student is given unknowns to identify.

Options: HCl NaOH NH4OH BaCl2 K2CrO4 AgNO3 NiSO4

(A) The unknown is colorless, odorless, and neutral. It produces no precipates when reacted with any of the three halides, Cl-, Br-, and I-. It produces a yellow precipate when added to sodium chromate. Which of the options could it be? Write it's exchange reaction with the sodium chromate. Specify the states.

(B) The unknown is colorless, odorless, and neutral. When mixed with NaOH it produced a brown precipitate and when mixed with BaCl2 it produced a white precipate. Reactions with other halides gave yellow precipitates. What unknown is it? Write the exchange reaction with the unknown and NaOH. Write the balanced reaction between the unknown and BaCl2. Specify the states in all reactions.

Explanation / Answer

HCl: Acidic

NaOH: Basic

  NH4OH : smell of NH3

BaCl2

BaCl2 + Na2CrO4 => BaCrO4 + 2NaCl

Ba2+ (aq)+ CrO42- (aq)=> BaCrO4 (s)

K2CrO4: Its yellow in color

  AgNO3

NiSO4 has a deep green color.

(A) The unknown is colorless, odorless, and neutral. It produces no precipates when reacted with any of the three halides, Cl-, Br-, and I-. It produces a yellow precipate when added to sodium chromate. Which of the options could it be? Write it's exchange reaction with the sodium chromate. Specify the states.

BaCl2

BaCl2 + Na2CrO4 => BaCrO4 + 2NaCl

Ba2+ (aq)+ CrO42- (aq)=> BaCrO4 (s)

BaCl2 produce does not precipates when reacted with any of the three halides, Cl-, Br-, and I- because Both species; BaCl2 and hailide are soluble in water.

(B) The unknown is colorless, odorless, and neutral. When mixed with NaOH it produced a brown precipitate and when mixed with BaCl2 it produced a white precipate. Reactions with other halides gave yellow precipitates. What unknown is it? Write the exchange reaction with the unknown and NaOH. Write the balanced reaction between the unknown and BaCl2. Specify the states in all reactions.

AgNO3(aq) + NaOH(aq) = AgOH(s) + NaNO3(aq)

                                             Brown

AgOH + BaCl2 = AgCl + Ba(OH)2

                             White

AlOH(aq) + BaCl2(aq) =AlCl2(s) + Ba(OH)2(aq)