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Calculate the change in Gibbs free energy for each of the following sets of Hrxn

ID: 1005560 • Letter: C

Question

Calculate the change in Gibbs free energy for each of the following sets of Hrxn, Srxn, and T. Hrxn= 81 kJ , Srxn= 153 J/K , T= 290 K Predict whether or not the reaction in part A will be spontaneous at the temperature indicated. Hrxn= 81 kJ , Srxn= 153 J/K , T= 756 K Predict whether or not the reaction in part B will be spontaneous at the temperature indicated. Hrxn= 81 kJ , Srxn= 153 J/K , T= 290 K Predict whether or not the reaction in part C will be spontaneous at the temperature indicated. Hrxn= 81 kJ , Srxn= 153 J/K , T= 392 K Predict whether or not the reaction in part D will be spontaneous at the temperature indicated.

Explanation / Answer

G = H - TS

If G is negataive then the reaction is spontaneous.

A) G = H - TS

          = 81 - (290*0.153) => 36.63 KJ. Reaction is non-spontaneous

B) G = H - TS

          = 81 - (756*0.153) => -34.67 KJ, Reaction is spontaneous.

C) G = H - TS

          = 81 - (290*-0.153) => 125.37 KJ , Reaction is non-spontaneous.

D) G = H - TS

          = -81 - (392*0.153) => -140.98 KJ, Reaction is spontaneous.

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