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In the formation of the ionic bond which gives stability to the potassium chlori

ID: 1024270 • Letter: I

Question

In the formation of the ionic bond which gives stability to the potassium chloride are involved energy steps which can be represented by Born-Haber cycle. The KCl forming reaction (s) and steps are mentioned below:(Make step by step)

Step I: Converting K (s) K (g); ?Hentalpia sublimation = + 90 kJ / mol
Step II: Dissociation ½ mole of Cl2 (g) in isolated atoms Cl (g); ?Hentalpia dedissociação = +121 kJ / mol
Step III: Ionization one mole of K atoms (g); ?Henergia ionization + = 419 kJ / mol
Step IV: Addition of 1 mol to 1 mol of electrons in single atoms of Cl (g); Electronic ?Hafirnidade = - 349 kJ / mol.
Step V: Combination 1 mol of K + ions (g) with 1 mole of chloride ions Cl- (g); DH = - 717 kJ / mol.
With respect to information and the above-mentioned data, it is correct to say that the standard enthalpy
formation of potassium chloride in kJ / mol is:

K(s) +1 /2 Cl2(g) KCl(s) AHfo = ?

Explanation / Answer

Formation of KCl by Born-Haber cycle,

dHof = 90 + 121 + 419 - 349 - 717 = -436 kJ/mol

the standard enthalpy of formation of KCl is,

B) -436 kJ/mol

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