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I need help with Chemistry Question no.6. Tks. prob0001pdf Adobe Acrobat Reader

ID: 1074851 • Letter: I

Question

I need help with Chemistry Question no.6. Tks.

prob0001pdf Adobe Acrobat Reader DC File Edit View Window Help Sign In Consider the bromination reaction of acetone CH,COCH3 + Br2CH3COCH2Br Determine the rate law and the rate constant from the following data [CH,COCH3|/M [Br2|/MHM initial rate Ms H+ Br Export PDF Create PDF v Edit PDF 1.00 2.00 2.00 1.00 1.00 1.00 2.00 2.00 1.00 1.00 1.00 2.00 4.00 x 10 8.00 x 10 8.00 x 10 8.00 x 103 Combine Files ^ Adobe Acrobat Pro DC Combine two or more files into a single POF 7, The reaction 0.100 M a. At what time is [A] 0.025 M? I. What is the rate of reaction when [A] A products is first order in A. Initially, A-0.800 M and after 54 min, A- Learn more organize Pages 0.025 M? Protect Optimize PDF The following first order reaction occurs in CCL o) at 45 °C: N2Og N-(), +22 (g), The rate constant is k-6.2 x10-s1. An 80.0 g sample of N205 in CCl4 o is allowed to decompose at 45 °C. a. How long does it take for the quantity of N2Os to be reduced to 2.5 g? b. How many liters of O2, measured at 745 mm Hg and 45 °C are produced up to this point? Fill& Sign Send for Signature Send & 1 rack Store and share files in the Document Cloud Learn More 1054 PM Type here to search e OChegg Study | Guid. aprob0001.pdf . Ado ^ 4x ENG 2018-01-12

Explanation / Answer

Answer 6) For the reaction , acetone +Br2---->products

Rate law gives,

Initial rate=k[acetone]^m *[Br2]^n where k=rate constant and n,m are the order of the reaction with respect to acetone and Br2 respectively.

putting the given data in the above equation,

4.00*10^-3 M/s=k*[1M]^m *[1M]^n .....................(1)

8.00*10^-3 M/s=k*[2M]^m *[1M]^n .....................(2)

8.00*10^-3 M/s=k*[2M]^m *[2M]^n .....................(3)

divide eqn (2) by (1),

2^1=(2)^m

m=1

now divide equation,(3) by (2),

1=(2)^n

log1=nlog2

n=0

now putting m=1 ,n=0 in eqn (1),

4.00*10^-3 M/s=k*[1M]

k=4.00*10^-3 s^-1

So rate equation, rate=k [acetone]

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