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On a hot summer day, you decide to make some iced tea. First, you brew 1.50 L of

ID: 1350156 • Letter: O

Question

On a hot summer day, you decide to make some iced tea. First, you brew 1.50 L of hot tea and leave it to steep until it has reached a temperature of Ttea = 75.0 C. You then add 0.975 kg of ice taken from the freezer at a temperature of Tice = 0C. By the time the mix reaches equilibrium, all of the ice has melted. What is the final temperature Tf of the mixture?

For the purposes of this problem, assume that the tea has the same thermodynamic properties as plain water.

The specific heat of water isc = 4190 J/kgC .

The heat of fusion of ice isLf = 3.33×105 J/kg .

The density of the tea istea = 1.00 kg/L .

Question:

You found that the final temperature of the iced tea is between 0 C and 75.0 C, as the strategy indicated it should be. Evaluate the work you did to find the final temperature by considering how it would change if the initial conditions were varied.

You decide to make several more batches of iced tea. The conditions under which you make these batches are identical except that for each batch one initial condition is varied. Determine the impact that each of these changes will have on the final temperature of the iced tea.

Decrease the volume of the tea.

Decrease the mass of ice.

Increase the initial temperature of the tea.

Decrease the initial temperature of the ice.

Sort these changes to the initial conditions of the system based on whether they would cause the final temperature to be smaller than or greater than the temperature of the system found in Part C.

Explanation / Answer

Given

Volume of tea V Tea = 1.50 L =

Temperature of Tea Ttea = 75o C

Temperature of ice Tice = 0o C

Mass of the ice mice =0.975 Kg

The specific heat of water is c = 4190 J/kgC

The heat of fusion of ice is Lf = 3.33×105 J/kg

The density of the tea is tea = 1.00 kg/L

Solution

Volume of the tea = 1.5 L

Mass of the tea = Vtea x tea

Mtea = 1.50 x 1.00

Mtea = 1.50 Kg

Heat lost by tea to reach temperature Tf = Heat absorbed by ice ( at 0oC) to melt into water (0oC) + Heat absorbed by water (at 0oC) to rach the final temperature Tf

MteaC(Ttea – Tf) = MiceLf + MiceC(Tf –Tice)

1.5 x 4190 x (75-Tf) = 0.975 x 3.33 x 105 + 0.975 x 4190 ( Tf)

471375 – 6285Tf = 324675 + 4085.25 Tf

Tf =146700 / 10370.25

Tf = 14.15 OC

MteaC(Ttea – Tf) = MiceL + MiceC(Tf –Tice)

MteaCTtea­ - MteaCTf = MiceL + MiceCTf - MiceCTice
MteaCTtea­ - MiceL + MiceCTice = MteaCTf + MiceCTf

MteaCTtea­ - Mice(L – CTice) = (MteaC+ MiceC)Tf

Tf = {MteaCTtea­ - Mice(L – CTice)} /(MteaC+ MiceC)

Decrease the volume of the tea.

The final temperature decreases since heat needed to be lost increases

Verification

Let us decrease the volume of tea to 1L

MteaC(Ttea – Tf) = MiceLf + MiceC(Tf –Tice)

1 x 4190 x (75-Tf) = 0.975 x 3.33 x 105 + 0.975 x 4190 ( Tf)

314250 – 4190Tf = 324675 + 4085.25 Tf

-10425 = 8272.25Tf

Tf = -1.26 oC

So the final temperature decreases

Decrease the mass of ice.

The final temperature increases since the heat needed to be lost decreases

Verification

Let us decrease the mass of the ice to 0.875 Kg

MteaC(Ttea – Tf) = MiceLf + MiceC(Tf –Tice)

471375 – 6285Tf = 291375 + 3666.25­Tf

Tf = 180000/9951.25 = 18.09oC

Increase the initial temperature of the tea.

The final temperature increases since the Tf is directly proportional to Ttea

Tf = {MteaCTtea­ - Mice(L – CTice)} /(MteaC+ MiceC)

Tf Ttea

Verification

increasing Ttea to 85oC

MteaC(Ttea – Tf) = MiceL + MiceC(Tf –Tice)

1.5 x 4190 x (85-Tf) = 324675 + 4085.25 Tf

502800 – 6285Tf = 324675 + 4085.25 Tf

Tf = 17.1oC

Decrease the initial temperature of the ice

The final temperature decreases since the Tf is directly proportional to Tice

Tf = {MteaCTtea­ - Mice(L – CTice)} /(MteaC+ MiceC)

Tf Tice

Verification

decreasing Tice to -10oC3

MteaC(Ttea – Tf) = MiceL + MiceC(Tf –Tice)

471375 – 6285Tf = 324675 + 4085.25 Tf + 4075.25

150775.25 = 10370.25 Tf

Tf = 13.75oC

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