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Calculating Equilibrium Concentrations The concentrations of reactants and produ

ID: 494027 • Letter: C

Question

Calculating Equilibrium Concentrations The concentrations of reactants and products for a chemical reaction can be calculated if the equilibrium constant for the reaction and the starting concentrations of reactants andor products are known. previous l 2 of 32 l next. Part A Carbonylfluoride, COFh, is an important intermediate used in the production of compounds. For instance, it is used to make the refrigerant carbon tetrafluoride, CF4 via the reaction 200F2 (g) t CO, (g) +CF4 (g), He 6.60 lf only COF2 is present initialy at a concentration of 200 M what concentration of coF, remains at equilibrium? Express the molar concentration numerically. Submit Hints My Answers Give Up Review Part Part B Consider the reaction CO(g) +NH3(g) a HCONH (g), Ke 0.760 If a reaction vessel initially contains only CO and NH3 at concentrations of 100 Mand 200 M respectively what will the concentration of H 2 be at equilibrium? Express the molar concentration numerically to three significant figures.

Explanation / Answer

                 2COF2-----------------> CO2 + CF4

    I             2                                 0         0

   C           -2x                               x          x

E           2-2x                              x          x

              Kc   = [CF4][CO2]/[COF2]^2

              6.6      = x*x/(2-2x)^2

              6.6     =( x/2-2x)^2

            2.57    = x/2-2x

          2.57*(2-2x) = x

              x= 0.84

        [COF2] = 2-2x = 2-2*0.84 = 0.32M

partB

            CO + NH3 -----------------> HCONH2

    I        1       2                               0

C        -x      -x                              +x

E        1-x   2-x                               +x

      Kc   = [HCONH2]/[CO][NH3]

      0.76   = x/(1-x)(2-x)

     0.76*(1-x)(2-x) = x

       x= 0.53

   [HCONH2] = x= 0.53M

            

             

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