The reaction of cyanide with thiosulfate has prepared the thiocyanate ion which,
ID: 495082 • Letter: T
Question
The reaction of cyanide with thiosulfate has prepared the thiocyanate ion which, when in acidic solution, bonds to the iron ions in iron(III) nitrate to form a deep red solution. Describe the resulting two-step procedure, including all reagents.
Step 1) Add [thiosulfate compound, thiosulfate and iron(III) nitrate, acid and iron(III) nitrate, iron(III) nitrate, thiosulfate compound and acid, acid] to the cyanide sample.
Step 2) Add [thiosulfate compound and acid, acid and iron(III) nitrate, acid, thiosulfate compound, thiosulfate and iron(III) nitrate, iron(III) nitrate] to the sample.
Explanation / Answer
Step 1) Add [thiosulfate compound, ] to the cyanide sample.
Step 2) Add [ acid and iron(III) nitrate, ] to the sample.
Cyanide + thiosulfate = thiocyanate
thiocyanate + iron (III) nitrate + acid = deep red solution
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