The reaction of cyclopropane to rearrange to propane has a rate constant of 5.65
ID: 793113 • Letter: T
Question
The reaction of cyclopropane to rearrange to propane has a rate constant of 5.65 s-1 at a certain temperature. How long does it take for the concentration of cyclopropane to decrease to one-quarter of its initial value?
Cyclopropane ? Propane, in which the coefficient for cyclopropane is one.
(Hint: the unit of the rate constant tells us that the reaction is 1st order.)
***Please give a step-by-step explaination! I don't even know how to start this. The answer should be in seconds. Thanks!!!***
Explanation / Answer
the reaction is 1st order so
let cyclopropane =A
r = K * [A] = -dA/dt
-dA/dt = K*[A]
integrating it we get
Kt = ln[A0] - ln[A]
[A0] = initial concentration of cyclopropane
Kt = ln([A0]/[A])
given [A0]/[A] = 4
t = ln4/K = 0.245 sec
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