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Name Desk Date Laboratory Instructor REPORT SHEET EXPERIMENT Titration of Acids

ID: 551188 • Letter: N

Question

Name Desk Date Laboratory Instructor REPORT SHEET EXPERIMENT Titration of Acids and Bases A. Standardization of Sodium Hydroxide (NaOH) Solution Trial 1 Trial 2 Trial 3 Mass of bottle +KHP Mass of bottle Mass of KHP used Final buret reading Initial buret reading mL of NaOH used Molarity ofNaOH Average molaty D1DE Sdard deviation 125 10 Show your calculations for molaritý and standard deviation. 00 0.10 0.106M· 43. : 01010 0.0/9 B. Analysis of an Unknown Acid Trial I Trial 2 Trial 3 Mass of bottle + unknown Mass of bottle Mass of unknown used Final buret reading Initial buret reading mL of NaOH used Mass of KHP in unknown . 14 Percent of KHP in unknown % KWP

Explanation / Answer

trial 1 :

moles of KHP used in the titration = 0.4190 gm/204.22 gmmol^-1 = 2.05*10^-3 moles

moles of NaOH = moles of KHP = 2.05*10^-3 moles

volume of NaOH used = 18 mL

molarity of NaOH = 2.05*10^-3 moles*1000mL/18mL = 0.113 M

trial 2 :

moles of KHP used in the titration = 0.426 gm/204.22 gmmol^-1 = 2.09*10^-3 moles

moles of NaOH = moles of KHP = 2.09*10^-3 moles

volume of NaOH used = 18 mL

molarity of NaOH = 2.09*10^-3 moles*1000mL/18.3mL = 0.114 M

trial 3 :

moles of KHP used in the titration = 0.439 gm/204.22 gmmol^-1 = 2.15*10^-3 moles

moles of NaOH = moles of KHP = 2.15*10^-3 moles

volume of NaOH used = 19.3 mL

molarity of NaOH = 2.15*10^-3 moles*1000mL/19.3mL = 0.111 M

Average = 0.113 M

Calculations for molarity and standard deviation:

M1=0.002mol/0.01950L=0.1026M

M2=0.002mol/0.01970L=0.1015M

M3=0.002mol/0.1980L=0.1010M

S=0.58(0.1026-0.1010)

=0.58*0.0016

=0.000928M

=9.28*10^-4M

B. Analysis of unknown acid :

trial1

moles of NaOH = 0.113 M *22.12mL/1000mL =2.5*10^-3 moles

moles of KHP = 2.5*10^-3 moles

mass of KHP = 2.5*10^-3 moles * 204.22 gm/mol = 0.510 gm

% = 0.510gm/0.99 *100 = 51.5 %

trial 2 :

moles of NaOH = 0.113 M *23.12mL/1000mL =2.61*10^-3 moles

moles of KHP = 2.61*10^-3 moles

mass of KHP = 2.61*10^-3 moles * 204.22 gm/mol = 0.533 gm

% = 0.533 gm/1gm *100 =53.3 5

trial 3:

moles of NaOH = 0.113 M *22.22mL/1000mL =2.51*10^-3 moles

moles of KHP = 2.51*10^-3 moles

mass of KHP = 2.51*10^-3 moles * 204.22 gm/mol = 0.512 gm

% = 51.2 %