11. Refer to instructions. The electrophile in this reaction is indicated by let
ID: 704407 • Letter: 1
Question
11. Refer to instructions. The electrophile in this reaction is indicated by letter_ f o r n ltiple Choice tify the choice that best completes the statement or answers the question 13. Many nucleophilic addition reactions of aldehydes and ketones are catalyzed b hydration by a. making the carbonyl group more electrophilic b. shifting the equilibrium of the reaction c. making the carbonyl group less electrophilic d. converting the water to hydronium ion, a much better nucleophile Instructions: Consider the reaction below to answer the following question. O. C HCI +HOCH CH2OH + H20 14. Refer to instructions. The product of this reaction is called: an ylide a. b. an acetal a gem diol d. c. a hydrate The nucleophillic addition of water to an aldehyde or ketone a. is irreversible b. dependent on the structure of the carbonyl. c. favored by neutral conditions. d. produces a stable tetrahedral product. e. all of these. 15.Explanation / Answer
13. d) converting the water to hydronium ion, a much better nucleophile.
Most reactions are catalysed by an acid or a base that changes water to hydronium ion which then adds to the ketone or aldehyde.
14. b) an acetal
Reaction of diol with a ketone gives cyclic acetal.
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