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Please help me by showing the work and the answer, because I\'m not understandin

ID: 837485 • Letter: P

Question

Please help me by showing the work and the answer, because I'm not understanding the material. Thanks.

Part A Carbonyl fluoride, COF2, is an important intermediate used in the production of fluorine-containing compounds. For instance, it is used to make the refrigerant carbon tetrafluoride, CF4 via the reaction 2COF2(g)? CO2(g)+CF4(g), Kc=7.80 If only COF2 is present initially at a concentration of 2.00 M, what concentration of COF2 remains at equilibrium? Express your answer with the appropriate units.

Part B

Consider the reaction

CO(g)+NH3(g)?HCONH2(g),    Kc=0.890

If a reaction vessel initially contains only CO and NH3 at concentrations of 1.00 M and 2.00 M, respectively, what will the concentration of HCONH2 be at equilibrium?

Express your answer with the appropriate units.

Explanation / Answer

Part A      

         2COF2(g)? CO2(g)+CF4(g)

initial.....................2.................0...............0

at equilibrium........2-x..............x...............x

KC=[CO2][CF4]/[COF2]2=x2/(2-x)2=7.8

x2=7.8(4+x2-4x)

0.1282x2=4+x2-4x

0=4+x2-0.1282x2-4x

0=4-0.87179x2-4x

(solve for x using quadratic formula) take positive value

x=0.844

hence equilibrium concentration of COF2=2.00-0.844=1.156M

Part B

                            CO(g)+NH3(g)?HCONH2(g),    Kc=0.890

initial.....................1...........2...............0

at equilibrium......1-x.......2-x...............x

Kc=x/(1-x)(2-x)=0.89(x2-3x+2)=x

x2-3x-1.12359x+2=0

x2-4.12359x+2=0 (solve for x using quadratic equation)

((((1-x)(2-x)=2-x-2x+x2=x2-3x+2)))

Hence concentration of HCONH2(g) at equilibrium will be

[HCONH2]=x=0.56

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