a) Use Table 18.a or Apendix C to calculate the Kb of the nitrite ion, NO2-? Sig
ID: 955928 • Letter: A
Question
a) Use Table 18.a or Apendix C to calculate the Kb of the nitrite ion, NO2-? Sig Figs
(b) What is Ka of the 2-hydroxyethylammonium ion, HOCH2CH2NH3+ (pKb of HOCH2CH2CH2NH2 = 4.49)? SIg Figs
Table 18.a below
Iodic acid-1.6x10-1
Chlorous acid-1.12x10-2
Nitrous acid 7.1x10-4
Hydrofluoric acid-6.8x10-4
Formic acid-1.8x10-4
Benzoic acid-6.3x10-5
acetic acid-1.8x10-5
Propanoic acid-1.3x10-5
Hypochlorous acid-2.9x10-8
Hypobromous acid-2.3x10-9
Hydrocyanic acid-6.2x10-10
Phenol-1.0x10-10
Hypoiodous acid-2.3x10-11
Explanation / Answer
a) Ka for HNO2 = 7.1 x 10^-4
Kb = Kw/Ka = 1 x 10^-14/7.1 x 10^-4 = 1.41 x 10^-11
b) pKb for 2-hydroxyethylammonium ion = 4.49
pKa = 14 - pKb = 14 - 4.49 = 9.51
pKa = -log[Ka]
Ka = 3.09 x 10^-10
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