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Calculate the G 0 rxn at35 0 C using the following information: 2H 2 S (g) + 3O

ID: 681622 • Letter: C

Question

Calculate the G0rxnat350C using the following information:                      2H2S(g)+ 3O2(g) 2SO2(g) +2H2O(g) Hof(kJ/mol)  -20.0      0               -296.8       -241.8 S0(J/mol)        205.8      205.2         248.2         188.8 Calculate the G0rxnat350C using the following information:                      2H2S(g)+ 3O2(g) 2SO2(g) +2H2O(g) Hof(kJ/mol)  -20.0      0               -296.8       -241.8 S0(J/mol)        205.8      205.2         248.2         188.8 Hof(kJ/mol)  -20.0      0               -296.8       -241.8 S0(J/mol)        205.8      205.2         248.2         188.8

Explanation / Answer

Formula:                  G0rxn = Ho - TS0                      Ho = Ho products - Ho reactants                       S0 = S0 products - S0 reactants                       Ho =(2 moles * -296.8 kJ / mol + 2 moles * -241.8 kJ / mol) - ( 2 moles * -20.0 kJ / mol + 3 moles * 0 kJ / mol )                              = (-593.6 kJ -483.6 kJ ) - ( -40 kJ )                              = -1037.2 kJ                      S0 = (2 moles * 248.2J /K mol +2 moles * 188.8 J /K. mol ) - ( 2 moles * 205.8 J /K mol + 3moles * 205.2 J /K. mol )                              =( 496.4 J/ K + 377.6 J / K ) - ( 411.6 J / K + 615.6 J / K)                              = -153.2 J / K                 T S0   = 308 K ( - 153.2 J /K)                              =-47.2 kJ             G0rxn =-1037.2 kJ - ( -47.2 kJ)                             = -990.0 kJ
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