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Calculate the change in pH for each buffer upon the addition of 10 mL of 1.00MHC

ID: 774670 • Letter: C

Question

Calculate the change in pH for each buffer upon the addition of 10 mL of 1.00MHCI. Express your answers using two decimal places. Enter your answers separated by a comma. Delta pHA, Delta pHB= Consider two buffers being prepared by adding an equal number of moles of formic acid (HCOOH) and sodium format (HCOONa) to enough water to make 1.00 L of solution. Buffer, A is prepared using 1.00 mol each of formic acid and sodium format. Buffer B is prepared by using 0.010 mol of each. Part A Calculate the pH of each buffer. Express your answers using two decimal places. Enter your answers separated by a comma. PHA,PHB= Try Again; 2 attempts remaining

Explanation / Answer

A)pHa=pka+log(salt/acid)

=pKa

=3.77

pHb=pKa+log(salt/acid)

=pKa

=3.77

D)intial pH=3.77

for A,

final pH=3.77+log((1-0.01)/(1+0.01))

=3.76

so change= -0.01

for B,

whole of the salt is converted to acid.so,

concentration of the acid=0.02

so let the dissociation be x.so,

10^(-3.77)=x^2/(0.02-x)

or x=0.00176

so pH=2.754

so change= -1.106

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